Qual O Serial Do Nero 3.1.0.25 In Portuguese, When Would You Use 'O Que' And 'Qual'?

In portuguese, when would you use 'O que' and 'Qual'? - qual o serial do nero 3.1.0.25

I know that means "or" what "and the other means" that ", but if you explicitly use one over the other?

For example, in "What é o seu nome?" Why is the "what" instead of "O"?

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